Switch between Email Addresses - Change the From Address
Firstly, open Outlook.
Now click on “New Email.”
Select the tab called “Options.”
Where it says “Show fields,” click on the option for “From.”
A new field called “From” will show up; click on the drop-down next.
Select the option for “Other email address.”
Now click on “From” again.
Select one of your email addresses and then click on “OK.”
Finally, click on “OK.”